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Heterogeneously Catalyzed Decarbonylation of Thioesters by Supported Nanoparticle Catalysts

16 February 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

This study demonstrated a heterogeneously catalyzed system for decarbonylation of various aryl thioesters to produce thioethers and CO by utilizing CeO2- or hydroxyapatite-supported Ni or Pd nanoparticle catalysts. The Ni catalysts showed high catalytic activity, while the Pd catalysts possessed excellent functional group tolerance.

Keywords

decarbonylation
nanoparticles
nickel
palladium
thioesters

Supplementary materials

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Description
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Title
Supporting Information for Heterogeneously Catalyzed Decarbonylation of Thioesters by Supported Nanoparticle Catalysts
Description
This supporting information contains experimental methods, spectral data, additional figures, additional tables, additional schemes, additional references, and NMR spectra.
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Now Published

Heterogeneously catalyzed decarbonylation of thioesters by supported Ni, Pd, or Rh nanoparticle catalysts [opens in a new tab]
Takehiro Matsuyama, Takafumi Yatabe, Kazuya Yamaguchi journal article
Organic & Biomolecular Chemistry , Volume 22, Issue 3
Online publication date: 2024

Version History

Feb 16, 2023 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-jn276
D O I: 10.26434/chemrxiv-2023-jn276 [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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