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Olefin Hydroboration catalyzed by an iron-borane complex

01 February 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The well-defined iron(0) complex [(iPrDPBPh)Fe2-(mu-1,2-N2)] (A) reacts with HBPin affords the complex [iPrDBPPh](-H)Fe(H)(BPin)2 via oxidative addition of the H-B bond. Complex A is an effective pre-catalyst for the hydroboration of a range of olefins in synthetically useful yields (typically >80%).

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Version History

Feb 01, 2023 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-nm4rh
D O I: 10.26434/chemrxiv-2023-nm4rh [opens in a new tab]

Funding

Engineering and Physical Sciences Research Council
EP/W023172/1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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