PCP Complexes of Titanium in the +3 and +4 Oxidation State

29 December 2022, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Ti(IV) and Ti(III) complexes using the tBuPCP ligand have been synthesised (tBuPCP = C6H3-2,6-(CH2PtBu2)2). The [tBuPCP]Li synthon can be reacted with TiCl4(THF)2 to form (tBuPCP)TiCl3 (1) in limited yields due to significant reduction of the titanium synthon. The Ti(III) complex (tBuPCP)TiCl2 (2) has been further characterised. This can have half an equivalent of halide abstracted to form [{(tBuPCP)TiCl}2{μ-Cl}][B(C6F5)4] (3) and can also be methylated forming (tBuPCP)TiMe2 (4). All the Ti(III) complexes have been characterised using EPR and x-ray crystallography, giving insight into their electronic structure, which is further supported by DFT calculations.

Keywords

Titanium
Pincer Ligands
Electron Paramagentic Resonance

Supplementary materials

Title
Description
Actions
Title
Supplementary Information
Description
Supplementary Information
Actions
Title
Coordinates File
Description
Coordinates File
Actions
Title
Crystal Structure Data
Description
Crystal Structure Data
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.