Carbon–Carbon Bond Formation from CO and H–
The Role of Metal Formyl Intermediates

Joseph Parr; Mark Crimmin

doi:10.26434/chemrxiv-2022-42m73

Organometallic Chemistry

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Carbon–Carbon Bond Formation from CO and H– The Role of Metal Formyl Intermediates

23 December 2022, Version 1

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Abstract

In this mini-review, we summarise the current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes. To date, the formation of both unsaturated and saturated C2 motifs along with cyclic C3 products has been reported. We discuss the mechanistic aspects of these reactions and the challenges and opportunities in using this understanding to underpin future FT chemistry.

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Version History

Dec 23, 2022 Version 1

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License

The content is available under CC BY 4.0

DOI

10.26434/chemrxiv-2022-42m73

Funding

Engineering and Physical Sciences Research Council

EP/S036628/1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content