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Abstract
The first total synthesis of (–)-merrillianin (1), which is a natural sesquiterpene with a tri- fused structure having a cyclopentane ring and five- and seven-membered lactone parts, is demonstrated. This asymmetric total synthesis enabled the absolute stereo structure determination of naturally occurring (–)-1.
Supplementary materials
Title
First_Total_Synthesis_of_Merrillianin_SI
Description
The synthetic procedures and NMR spectra were herein.
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