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Abstract
Cross-pinacol coupling of two different carbonyl compounds was achieved through successive one-electron transfer processes under photocatalytic conditions. In this process, an umpoled anionic carbinol synthon was generated in situ to react nucleophilically with a second electrophilic carbonyl compound. A wide variety of aromatic and aliphatic aldehydes and ketones were tolerated to afford the corresponding unsymmetric vicinal 1,2-diols.
Supplementary materials
Title
Supporting Information; Photocatalytic Cross-Pinacol Coupling
Description
Experimental procedures, characterization data, and
spectroscopic data.
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