Off Detailed Balance: Non-Equilibrium Steady States in Catalysis, Molecular Motors and Supramolecular Materials

29 November 2022, Version 2
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

All chemists are familiar with the idea that, at equilibrium steady state, the relative concentrations of species present in a system are predicted by the corresponding equilibrium constants, which are in turn related to the relative free energy difference of the system components. There is also no net flux between species, no matter how complicated the reaction network. Achieving and harnessing non-equilibrium steady states, by coupling a reaction network to a second spontaneous chemical process, has been the subject of work in a number of disciplines including the autonomous operation of molecular motors, the assembly of supramolecular materials, and strategies in enantioselective catalysis. Here we juxtapose these linked fields to highlight their common features, the similar issues that must be overcome, and some common misconceptions that may be serving to stymie progress.

Keywords

Molecular machines
Non-equilibrium steady states
Supramolecular polymers
Catalysis

Supplementary materials

Title
Description
Actions
Title
Electronic supporting information
Description
Derivation of equations and further discussion.
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.