A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

08 August 2022, Version 1

Abstract

The synthesis and characterisation of [Co2(η4 P2C2tBu2)2(µ:η4:η4-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands.

Content

Supplementary materials

Electronic Supplementary Information
Synthesis and characterization of compound 1; NMR, UV-vis, cyclic voltammety and mass spectrometric data, single X-ray crystallographic data, and results of quantum chemical calculations.

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.