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Site-selective Electrochemical Oxidation of Glucosides

01 August 2022, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with excellent selectivity. The method is a versatile alternative to Pd-catalyzed oxidation, and to photochemical oxidation, and is complementary to the TEMPO-mediated C6-selective oxidation. Contrary to the electrochemical oxidation of methylene and methine groups, the reaction does not require oxygen.

Keywords

Glucosides
site-selective modification
oxidation

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Version History

Aug 01, 2022 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-gg3g5
D O I: 10.26434/chemrxiv-2022-gg3g5 [opens in a new tab]

Funding

ARC CBBC
-

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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