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An [FeIII8] molecular oxyhydroxide

04 May 2022, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

An [FeIII8] hexagonal bipyramid, which represents an all ferric piece of molecular magnetite, displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state, S = 10.

Keywords

iron
molecular metal oxide
magnetism
cluster
ferrimagnetic

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Version History

May 04, 2022 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-bqwk3
D O I: 10.26434/chemrxiv-2022-bqwk3 [opens in a new tab]

Funding

Engineering and Physical Sciences Research Council
EP/V010573/1
Marie Skłodowska-Curie
832488

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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