An [FeIII8] molecular oxyhydroxide

Euan Brechin; Daniel Cutler; Marco Coletta; Mukesh Singh; Angelos Canaj; Laura McCormick; Simon Coles; Jürgen Schnack

doi:10.26434/chemrxiv-2022-bqwk3

Inorganic Chemistry

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An [FeIII8] molecular oxyhydroxide

Working Paper

Euan Brechin University of Edinburgh ,
Daniel Cutler University of Edinburgh ,
Marco Coletta University of Edinburgh ,
Mukesh Singh University of Edinburgh ,
Angelos Canaj University of Edinburgh ,
Laura McCormick University of Southampton ,
Simon Coles University of Southampton ,
Jürgen Schnack Bielefeld University

Abstract

An [FeIII8] hexagonal bipyramid, which represents an all ferric piece of molecular magnetite, displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state, S = 10.

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May 04, 2022 Version 1

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The content is available under CC BY 4.0 License CreativeCommons.org

DOI

10.26434/chemrxiv-2022-bqwk3

Funding

Engineering and Physical Sciences Research Council

EP/V010573/1

Marie Skłodowska-Curie

832488

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

Keywords

iron

molecular metal oxide

magnetism

cluster

ferrimagnetic

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This content is an early or alternative research output and has not been peer-reviewed at the time of posting.

An [FeIII8] molecular oxyhydroxide

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Abstract

Content

Version History

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License

DOI

Funding

Author’s competing interest statement

Ethics

Keywords

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