Materials Chemistry

Ambient-stable near Unity Photoluminescence Quantum Yield in Two-dimensional Tin Bromide Perovskites

Authors

  • ARNAB MANDAL Indian Institute of Science Education and Research Kolkata ,
  • SAMRAT ROY Indian Institute of Science Education and Research Kolkata ,
  • ANAMIKA MONDAL Indian Institute of Science Education and Research Kolkata ,
  • BIPUL PAL Indian Institute of Science Education and Research Kolkata ,
  • SAYAN BHATTACHARYYA Indian Institute of Science Education and Research Kolkata

Abstract

Semiconductor nanostructures with near-unity photoluminescence quantum yields (PLQYs) are imperative for light-emitting diodes and display devices.With 1,8 diaminooctane (8N8) interlayer spacer, the Dion-Jacobson (8N8)SnBr4 (8N8-DJ) perovskite demonstrates a PLQY of 99.7±0.3%. The near-unity PLQY of 8N8-DJ has outstanding ambient stability for over a month throughout the entire excitation wavelength range. By changing the spacer to n-octylamine (8N), Ruddlesden-Popper (8N)2SnBr4 (8N-RP) also has an appreciable PLQY of 91.7±0.6%. However, the PLQY of 8N-RP is unstable under ambient conditions due to increased lattice strain and structural degradation of the perovskite phase. The PL experiments from 5K to 300K decipher the room temperature PLQY to be due to the self-trapped emission (STE) where the self-trapping depth is 25.6±0.4 meV below the conduction band as a result of strong carrier-phonon coupling. With 34.7-37.3meV exciton binding energy, the ~5.5 s long-lived STE emission dominates over the band edge (BE) peaks at lower excitation wavelengths and higher temperatures. The higher PLQY and stability of 8N8-DJ are due to the stronger interaction between SnBr64- octahedra and 1,8 diammonium octane cation leading to a more rigid structure. The near-unity PLQY of 8N8-DJ remains unchanged from its powder form to the polymer-embedded perovskite films with varying thicknesses.

Content

Thumbnail image of 2022-04-28 DJ-RP-PLQY Manuscript final color.pdf

Supplementary material

Thumbnail image of 2022-04-28DJ-RP-PLQY Manuscript final color_SI.pdf
Supporting Information
AFM, SEM and TEM images; elementary mapping; XPS results; UV and PLE stability; low temperature PL experimental setup; temperature dependent PL spectra and PL peak energy plots; exciton binding energy; FWHM analysis; 8N-RP PL reversibility; FTIR spectra; XRD stability test; digital images; PL lifetime; comparison tables.