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Decarbonylative Reductive Coupling of Aromatic Esters by Nickel and Palladium Catalyst

26 April 2022, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Ni or Pd-catalyzed decarbonylative reductive couplings of aromatic esters were developed. A range of (hetero)aromatic esters was applicable to these reductive homocoupling reactions. Moreover, it was found that Pd-catalysis enables a reductive decarbonylative cross-coupling between two different aromatic esters to afford a nonsymmetrical biaryls system.

Keywords

Decarbonylative
homocoupling
palladium
nickel
biaryls
aromatic esters

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Version History

Apr 26, 2022 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-s0sxl
D O I: 10.26434/chemrxiv-2022-s0sxl [opens in a new tab]

Funding

Japan Society for the Promotion of Science
JP21H05213
Japan Society for the Promotion of Science
JP21K05079
Japan Society for the Promotion of Science
JP19J23053
Exploratory Research for Advanced Technology
JPMJER1901

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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