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Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Al-kyltitanium Alkoxides with Aryl and Alkenyl Halides

17 March 2022, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A light-promoted photocatalyst-free nickel-catalyzed cross-coupling of alkyltitanium alkoxides with aryl and alkynyl halides is reported. The organotitanium reagents were generated in situ from titanium(IV) isopropoxide and Grignard reagents.

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Version History

Mar 17, 2022 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-k808c
D O I: 10.26434/chemrxiv-2022-k808c [opens in a new tab]

Funding

State Program for Scientific Research (Belarus)
2.2.01.07 (520/42)

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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