Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Al-kyltitanium Alkoxides with Aryl and Alkenyl Halides

17 March 2022, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A light-promoted photocatalyst-free nickel-catalyzed cross-coupling of alkyltitanium alkoxides with aryl and alkynyl halides is reported. The organotitanium reagents were generated in situ from titanium(IV) isopropoxide and Grignard reagents.

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