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Abstract
A novel 22π-aromatic sapphyrin isomer endowed with acene moiety is designed and realized for the first time as its core-modified mono-thia analogue. This macrocycle exhibits absorption and emission in the near infrared region. It was diprotonated under strong acidic condition, then it binds anion like sapphyrin. It shows unusual coordination chemistry by acting as a neutral ligand to undergo large out-of-plane deformation to bind Pd (II) ion.
Supplementary materials
Title
Monothia [22]pentaphyrin(2.0.1.1.0): A core modified isomer of Sapphyrin
Description
Electronic supplementary information contains synthetic procedures, characterization, crystallographic parameters and computational data including coordinates.
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