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TEM study of boron phosphide: Discovery of rhombohedral BP

07 December 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Microstructure of sphalerite (3C) boron phosphide, BP, produced by self-propagated high-temperature synthesis has been studied by high-resolution transmission electron microscopy. Along with numerous twins on the {111}3C plane, layers of wurtzite (2H) polymorphic modification and previously unknown for BP rhombohedral (3R) structure were found which indicates trimorphism of BP.

Keywords

boron phosphide
transmission electron microscopy
polymorphism
twinning

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Now Published

TEM study of boron phosphide: Discovery of rhombohedral BP [opens in a new tab]
B.A. Kulnitskiy, V.D. Blank, T.A. Gordeeva, V.A. Mukhanov, V.L. Solozhenko journal article
Solid State Communications , Volume 354
Print publication date: Oct, 2022

Version History

Dec 07, 2021 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-qkn56
D O I: 10.26434/chemrxiv-2021-qkn56 [opens in a new tab]

Funding

Agence Nationale de la Recherche - France
ANR-20-ASTR-0020

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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