Polyethylene Glycol Wrapped Alginate/Graphene Hollow Microfibers as Flexible Supercapacitors

08 November 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Carbon-modified fibrous structures with high biocompatibility have attracted much attention as supercapacitors due to their low cost, sustainability, abundance, and excellent electrochemical performance. However, some of these carbon-based materials suffer from low specific capacitance and electrochemical performance, which have been significant challenges in developing biocompatible electronic devices. In this regard, several studies have been reported on the development of 3D carbon-based micro architectures that provided high conductivity, energy storage potential, and 3D porosity frameworks. This study reports manufacturing of microfluidic Alginate hollow microfiber modified by water-soluble modified Graphene (BSA-Graphene). These architectures successfully exhibited conductivity enhancement conductivity of about 20 times more compared to Alginate hollow microfibers, and without any significant change in the inner-dimension values of hollow region (220.0 ± 10.0 µm) in comparison with pure alginate hollow microfibers. In the presence of Graphene, more obtained specific surface permeability and active ion adsorption sites could successfully provide as shorter pathways. These obtained continuous ion transport networks resulted in improved electrochemical performance. These desired electrochemical properties of the microfibers make Alginate/Graphene hollow fibers an excellent choice for further use in the development of lightweight flexible supercapacitors with scalable potential to be used in intelligent health electronic gadgets.

Keywords

Alginate/Graphene
hollow microfibers
Conductivity
Super-capacitor
Microfluidics

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