Tuning the Electrochemical and Photophysical Properties of Osmium Complexes for Application in Photoredox Catalysis

22 October 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Photocatalysis driven by visible and ultraviolet irradiation is a fundamental tool for synthetic chemists. Recently, expansion of this tool to near-infrared (NIR) light has gained in popularity. Herein, we report the detailed photophysical characterization of a library of OsII polypyridyl photosensitizers that absorb NIR irradiation. By tuning ligand scaffold and electron density, we access a range of synthetically useful excited state energies and redox potentials.

Keywords

photoredox catalysis
near-infrared
ligand design

Supplementary materials

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Experimental details and compound characterization
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