Lower Heating Value of Jet Fuel from Hydrocarbon Class Concentration Data and Thermo-Chemical Reference Data: An Uncertainty Quantification

15 October 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A detailed assessment is presented on the calculation and uncertainty of the lower heating value (net heat of combustion) of conventional and sustainable aviation fuels, from hydrocarbon class concentration measurements, reference molecular heats of formation, and the uncertainties of these reference heats of formation. Calculations using this paper’s method and estimations using ASTM D3338 are reported for 17 fuels of diverse compositions and compared against reported ASTM D4809 measurements. All the calculations made by this method and the reported ASTM D4809 measurements agree (i.e., within 95% confidence intervals). The 95% confidence interval of the lower heating value of fuel candidates that are comprised entirely of normal- and iso-alkanes is less than 0.1 MJ/kg by the method described here, while high cyclo-alkane content leads to 95% confidence bands that approach 0.2 MJ/kg. Taking a possible bias into account, the accuracy and precision of the method described in this work could be as high as 0.23 MJ/kg for some samples.

Keywords

Lower Heating Value
Sustainable Alternative Fuel
GCxGC
Thermo-chemical Reference Data

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.