Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines

Cara Aversa-Fleener; Daniel Chang; Allegra Liberman-Martin

doi:10.26434/chemrxiv-2021-zfvc9

Working Paper

Abstract

We report the use of a cyclic carbodiphosphorane catalyst for ketone and imine hydroboration reactions. To our knowledge, this represents the first use of a carbodiphosphorane as an organocatalyst. The carbodiphospohorane shows superior catalytic activity compared to other neutral carbon nucleophiles tested.

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Supplementary material

Supporting Information for "Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines"

Contains synthetic procedures, NMR data, and NMR spectra

Now Published

Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines

Cara R. Aversa-Fleener, Daniel K. Chang, Allegra L. Liberman-Martin journal article

Organometallics , Volume 40, Issue 24

Online publication date: Dec 16, 2021

Version History

Oct 20, 2021 Version 1

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The content is available under CC BY NC ND 4.0 License CreativeCommons.org

DOI

10.26434/chemrxiv-2021-zfvc9

Funding

American Chemical Society Petroleum Research Fund

62239-UNI1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Keywords

Lewis base catalysis

hydroboration

main group chemistry

Publication

This content is an early or alternative research output and has not been peer-reviewed at the time of posting.