Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines

20 October 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the use of a cyclic carbodiphosphorane catalyst for ketone and imine hydroboration reactions. To our knowledge, this represents the first use of a carbodiphosphorane as an organocatalyst. The carbodiphospohorane shows superior catalytic activity compared to other neutral carbon nucleophiles tested.

Keywords

Lewis base catalysis
hydroboration
main group chemistry

Supplementary materials

Title
Description
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Title
Supporting Information for "Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines"
Description
Contains synthetic procedures, NMR data, and NMR spectra
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