Diketopyrrolopyrrole (DPP)-based polytriazoles: Synthesis and Immobilization by click reaction†

12 October 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Diketopyrrolopyrrole-based polymers are generally immobilized to various surfaces for device fabrications and sensor applications. preparative methods as well as Immobilization processes play a significant role for device efficacy. In this paper, we demonstrated that while "click" polymerization can be conveniently used for the preparation of diketopyrrolopyrrole DPP-based polymer, self-assembled monolayer (SAM) formation technique is convenient for efficient Immobilization to surfaces. Computational models have been used to theoretically calculate various energy parameters. Finally, some of those surfaces have been used as reusable photocatalytic chips, in line with mechanistically similar photovoltaic chips

Keywords

Click Rea
Click Reaction
Diketopyrrolopyrrole
Surface
Self-Assembled Monolayer (SAM)
Photocatalysis
Theoretical
computational
Morphology

Supplementary materials

Title
Description
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Title
ESI
Description
Detailedexperimental procedures for synthesis of monomers and surfaces functionalization and its 1H and 13C NMR spectra, Characterization of Zno based photocatalysts and the detailed experimental procedure of photocatalytic dye degradation processwere available in ESI
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