Azetidinium lead halide Ruddlesden-Popper phases

30 September 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A family of Ruddlesden-Popper (n = 1) layered perovskite-related phases, Az2PbClxBr4-x with composition 0 ≤ x ≤ 4 were obtained using mechanosynthesis. A linear variation in unit cell volume as a function of anion average radius is observed. A tunable bandgap is achieved, ranging from 2.81 to 3.43 eV, and the bandgap varies in a second order polynomial relationship with the halide composition.

Keywords

layered perovskite
bandgap tuning
azetidinium
Ruddlesden-Popper
structure-property relations

Supplementary materials

Title
Description
Actions
Title
ESI
Description
Electronic Supporting Information
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.