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Abstract
Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt-linked M6L3 nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in Co(I), Co(II), and Co(III) states.
Supplementary materials
Title
Supplementary Information
Description
Details of syntheses and experiments. UV-vis, 1H NMR, 13C{1H}, and DOSY NMR spectra. ESI-MS data. Cyclic voltammograms.
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