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meso-Antracenyl-BODIPY dyad as a new photocatalyst in ATRA reac-tions

30 August 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We demonstrate that because of the efficient generation of triplet excited state under UV or visible-light irradiation, meso-antracenyl-BODIPY donor-acceptor dyad can catalyze ATRA reactions between bromomalonate and alkenes. This finding paves the way for the design and application of the new type of heavy atom-free organic chromophores for photocatalysis.

Keywords

Donor-Acceptor dyad
BODIPY
triplet state
ATRA
Photocatalysis

Supplementary materials

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Description
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Supporting Information
Description
Experimental details and spectral characterizations of the catalysts and obtained compounds.
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Now Published

meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions [opens in a new tab]
Sara Abuhadba, Miu Tsuji, Tomoyasu Mani, Tatiana V. Esipova journal article
ACS Omega , Volume 6, Issue 48
Online publication date: Nov 19, 2021

Version History

Aug 30, 2021 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-899lq
D O I: 10.26434/chemrxiv-2021-899lq [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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