Authors
- Tanner Jankins Scripps Research Institute ,
- Raul Martin-Montero Institut Català d'Investigació Química ,
- Phillippa Cooper Scripps Research Institute ,
- Ruben Martin Institut Català d'Investigació Química ,
- Keary Engle
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Scripps Research Institute
Abstract
A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp3)–H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.
Content
Supplementary material
Supporting Info
Experimental Procedures, Analytical Data, and Copies of NMR Spectra
2b.cif
Crystallographic Information File - Compound 2b
2i.cif
Crystallographic Information File - Compound 2i
2n.cif
Crystallographic Information File - Compound 2n
3b.cif
Crystallographic Information File - Compound 3b
