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A Convenient Synthesis of Thiol, Trithiocarbonate and Disulfide

28 June 2021, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Synthesis of unsymmetrical trithiocarbonate sulfonate salt, along with disulfide, thiol and
symmetrical trithiocarbonate from 3-mercapto-1-propane-sulfonicacid, sodium salt with, without
of phase transfer catalyst and under various reaction conditions are described. The obtained
compounds having divergent usefulness in RAFT polymerization, sulfonyl preparation and
having capable of binding in a multidentate fashion to soft transition metal ions.

Keywords

Symmetrical Disulfides
trithiocarbonate RAFT agent
thiol
sulfonate salts.
unsymmetrical trithiocarbonates
symmetrical trithiocarbonates
Unsymmetrical Disulfides

Supplementary materials

Title
Description
Actions
Title
THIOL manuscript with C2, ready to submit to Chemrxiv on 6-27-2021
Description
Thiol Manuscript
Actions
Title
Thiol-spectral data with C2, ready to submit for chemrxiv on 6-27-21
Description
Thiol Spectral data
Actions

Supplementary weblinks

Title
Description
Actions
Title
Convenient Synthesis of Thiol, Trithiocarbonate and Disulfide
Description
Convenient Synthesis of Thiol, Trithiocarbonate and Disulfide from same starting material, substrate by using different reaction conditions
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Version History

Jun 28, 2021 Version 2

Version Notes

Included two carbon sulfonate reactions, which gives acid substrate sulfonate salt without PTC.

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-rrmw2-v2
D O I: 10.26434/chemrxiv-2021-rrmw2-v2 [opens in a new tab]

Funding

S.R.G is thanks to Professor Brent Sumerlin for supporting to complete the project.
The authors thank the National Science Foundation and the Welch Foundation for support of this work.

Author’s competing interest statement

The authors declare that they have no known competing financial interests.

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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