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A Convenient Synthesis of Dithiolane and Benzyloximates Derivatives for Ligand Studies

15 June 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the synthesis of new aromatic derivatives containing the 1,3-dithiolane ether and benzyloximino moiety which are attached by simple alkylation and esterification reaction by treating 1,3-dithiolane-2-methanol and a-benzyloximino acid chloride respectively with various aromatic halides and alcohols, respectively. The isolated yields of these compounds range from 65 to 85%. 1,3-dithiolane ether and the benzyloxy substituted hydroquinone are white solids or residual oil and stable to air and moisture.

Keywords

dithiolane
benzyloximate
ligands
multidentate amine molecules

Supplementary materials

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diimine and dithialone-spectral data ready to submit to chemrxiv
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Version History

Jun 15, 2021 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14776350.v1
D O I: 10.26434/chemrxiv.14776350.v1 [opens in a new tab]

Funding

The authors thank the National Science Foundation and the Welch Foundation for support of this work.

Author’s competing interest statement

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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