Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

A Convenient Synthesis of Dithiolane and Benzyloximates Derivatives for Ligand Studies

15 June 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the synthesis of new aromatic derivatives containing the 1,3-dithiolane ether and benzyloximino moiety which are attached by simple alkylation and esterification reaction by treating 1,3-dithiolane-2-methanol and a-benzyloximino acid chloride respectively with various aromatic halides and alcohols, respectively. The isolated yields of these compounds range from 65 to 85%. 1,3-dithiolane ether and the benzyloxy substituted hydroquinone are white solids or residual oil and stable to air and moisture.

Keywords

dithiolane
benzyloximate
ligands
multidentate amine molecules

Supplementary materials

Title
Description
Actions
Title
diimine and dithialone-spectral data ready to submit to chemrxiv
Description
Actions

Supplementary weblinks

Title
Description
Actions
Title
Description
Actions
View
Title
Description
Actions
View

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Jun 15, 2021 Version 1

Metrics

780
289
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14776350.v1
D O I: 10.26434/chemrxiv.14776350.v1 [opens in a new tab]

Funding

The authors thank the National Science Foundation and the Welch Foundation for support of this work.

Author’s competing interest statement

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Share