Sulfonium Ion-Promoted Traceless Schmidt Reaction of Alkyl Azides

26 May 2021, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction showcased ring-opening, -expansion, and one-pot further conversion of the substrates as well as the application with C-H azidation.

Keywords

Organic Azides Reactions
C-C bond cleavage

Supplementary materials

Title
Description
Actions
Title
Bayu ManuscriptForChemRxiv SI
Description
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.