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Trapping an Unusual Pentacoordinate Carbon Atom in a Neutral Trialuminum Complex

12 May 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al 3 core stabilizes the
hypercoordinate carbon atom resulting in the shortest equatorial Al–C distance reported for such systems.

Keywords

pentacoordinate carbon
neutral aluminum complex
methylidene
reaction dynamics studies

Supplementary materials

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Version History

May 12, 2021 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14552553.v1
D O I: 10.26434/chemrxiv.14552553.v1 [opens in a new tab]

Funding

FONDECYT 1200748
FONDECYT-ANID Postdoctorado 3210532
FONDECYT-ANID Postdoctorado 3180073
FONDECYT 1181260

Author’s competing interest statement

No conflict of interest

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