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1,2-Dicarbonyl Radicals with Exceptional Physiological and Chemical Stability

29 July 2020, Version 1

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Abstract

The present manuscript describes the design, synthesis, and characterization of the most stable organic radical reported up to date.

Here we report:

▪ Synthesis and full characterization including X-ray structure of stable 1,2-dicarbonyl radicals

▪ Proposed mechanism for the formation of the presented radicals

▪ Redox reactivity of the radicals

▪ Stability of the radicals under various organic and inorganic conditions

▪ Demonstration of the radicals as potential organic radical contrast agent candidate

Keywords

N-Heterocyclic Carbene

Supplementary materials

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Description

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Title

SI-14

Description

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May 11, 2021 Version 2

Jul 29, 2020 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.12732011.v1

Author’s competing interest statement

A patent application has been led through POSTECH on methods and reagents presented in this manuscript.

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