Mapping Wave Packet Bifurcation at a Conical Intersection in CH3I by Attosecond XUV Transient Absorption Spectroscopy

Extreme ultraviolet (XUV) transient absorption spectroscopy has emerged as a sensitive tool for mapping the real-time structural and electronic evolution of molecules. Here, attosecond XUV transient absorption is used to track dynamics in the A-band of methyl iodide (CH₃I). Gaseous CH₃I molecules are excited to the A-band by a UV pump (277 nm, ∼20 fs) and probed by attosecond XUV pulses targeting iodine I(4d) core-to-valence transitions. Owing to the excellent temporal resolution of the technique, passage through a conical intersection is mapped through spectral signatures of nonadiabatic wave packet bifurcation observed 15 ± 4 fs following UV photoexcitation. The observed XUV signatures and time dynamics are in agreement with previous simulations [H. Wang, et al. J. Chem. Phys. 151, 124106 (2019)]. Due to the short duration of the UV pump pulse, coherent vibrational motion in the CH₃I ground state along the C-I stretch mode (538 ± 7 cm^-1) launched by resonant impulsive stimulated Raman scattering and dynamics in multiphoton excited states of CH₃I are also detected.