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Requirements of Orbital Phase Continuity Revisited: A FMO Approach

02 April 2021, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Cyclic orbital interaction, in which a series of orbitals interact with each other so as to make a monocyclic system, affords stabilization if the requirements of orbital phase continuity are satisfied. Initially, these requirements were derived from the consideration of a three-body system. Here I propose that these requirements can be easily derived by considering FMO theory.

Keywords

Requirements of phase continuity
Orbital phase theory
Cyclic orbital interaction
FMO theory

Supplementary materials

Title
Description
Actions
Title
ReqPhaseCont1331
Description
Actions

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Version History

Apr 02, 2021 Version 2

Version Notes

ver 2 fixing a typo in the title

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14345639.v2
D O I: 10.26434/chemrxiv.14345639.v2 [opens in a new tab]

Author’s competing interest statement

There is no conflict of interest.

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