Catalysis

(2-Fluoroallyl)pyridinium Tetrafluoroborates: Novel Fluorinated Electrophiles for Pd-Catalyzed Allylic Substitution

Authors

Abstract

An efficient two-step approach to 2-fluoroallyl amines was developed that involves the synthesis of (2-fluoroallyl)pyridinium tetrafluoroborates from readily available gem-bromofluorocyclopropanes and the application of the former as novel and stable 2-fluoroallyl electrophiles for Pd-catalyzed allylic substitution

Content

Thumbnail image of Manuscript_ChemRxiv.pdf

Supplementary material

Thumbnail image of ESI - Experimental procedures.pdf
ESI - Experimental procedures
Thumbnail image of ESI-NMR.pdf
ESI-NMR