Inorganic Chemistry

Synthetic Approaches for Accessing Rare-Earth Analogues of UiO-66

Abstract

Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and demonstrate a high degree of crystallinity, high surface area and thermal stability, consistent with the UiO-66 archetype.

Content

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Supplementary material

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Donnarumma final SI 2