Organic Chemistry

Manganese Catalyzed Anti-Markovnikov Hydroamination of Allyl Alcohols via Hydrogen Borrowing Catalysis

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Abstract

A phosphine ligand free manganese(I)-complex catalyzed the selective anti-Markovnikov hydroamination of allylic alcohols via waste-free hydrogen transfer mechanism. The γ-amino alcohol products are versatile synthetic intermediates for the synthesis of several drug molecules.

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Supplementary material

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SI