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Time-Resolved UV-IR Experiments that Suggest Photoactivated Fe-Cu Dinuclear Catalyst

09 March 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

This work reports the synthesis of a triethylsilyl-substituted Fe-Cu complex that provided cyclohexane solubility to conduct time-resolved UV-IR studies. These studies suggest that UV light induces a photochemically active heterodinuclear species for arene borylation catalysis.

Keywords

heterodinuclear catalysts
heterobimetallic complex
UV-IR

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Now Published

Time-Resolved Ultraviolet–Infrared Experiments Suggest Fe–Cu Dinuclear Arene Borylation Catalyst Can Be Photoactivated [opens in a new tab]
Jacob T. Davis, Erin E. Martinez, Kyle J. Clark, Doo-Hyun Kwon, Michael R. Talley, David J. Michaelis, Daniel H. Ess, Matthew C. Asplund journal article
Organometallics , Volume 40, Issue 12
Online publication date: Jun 09, 2021

Version History

Mar 09, 2021 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14176646.v1
D O I: 10.26434/chemrxiv.14176646.v1 [opens in a new tab]

Funding

CHE-1764194
CHE-1665015

Author’s competing interest statement

No conflict of interest.

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