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Aminobismuthination of CO2

25 January 2021, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the facile (25 oC, 1 atm, <5 minutes) and selective insertion of CO2 into Bi-N bonds to yield bismuth carbamates. The role of ligand and substituent on promoting the controlled aminobismuthination of CO2 and rendering the bismuth carbamate products stable against thermal decomposition and ligand degradation is revealed.

Keywords

CO2 functionalization
bismuth
amides
main group chemistry
p-block chemistry

Supplementary materials

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Version History

Jan 25, 2021 Version 2

Version Notes

Version 2.0

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License

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.13619180.v2
D O I: 10.26434/chemrxiv.13619180.v2 [opens in a new tab]

Author’s competing interest statement

None

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