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Resorcin[4]arene-Based Multidentate Phosphate Ligands with Superior Binding Affinity for Nanocrystal Surfaces

13 January 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We designed and synthesized two resorcin[4]arene scaffolds with four phosphoric acid binding groups. The ligands effectively bind in at least a tridentate fashion. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of phosphonic acids.

Keywords

macrocycle
nanocrystal
zirconia
surface chemistry

Supplementary materials

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Version History

Jan 13, 2021 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.13567430.v1
D O I: 10.26434/chemrxiv.13567430.v1 [opens in a new tab]

Funding

SNF NCCR molecular systems engineering (SNF project number: 182895)

Author’s competing interest statement

No conflict of interest

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