Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

O-Mesityl(sulfonyl)hydroxylamine: A Novel Reagent for Reduction of Electron Deficient α,β-Unsaturated Carbonyl Derivatives

31 December 2020, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Hydrogenation of electron deficient ,-unsaturated carbonyl derivatives
using O-mesityl(sulfonyl)hydroxylamine in the presence of catalytic amount of ytterbium
triflate to obtain good to excellent is described.

Keywords

O-mesityl(sulfonyl)hydroxylamine (MSA),
,-unsaturated carbonyl,
Hydrogenation,
Yb(OTf)3,
selectivity.

Supplementary materials

Title
Description
Actions
Title
Hydrogenation-a,b-unsaturated substrates-experimental 12-29-2020
Description
Actions
Title
Hydrogenation-a,b-unsaturated substrates-spectral data-12-29-2020
Description
Actions
Title
Hydrogenation-Experimental on 12-28-2020, endnote ref
Description
Actions
Title
Hydrogenation-products NMR and Mass data on 12-28-2020
Description
Actions
Title
Stability study of sulfonoyl hydroxylamine derivatives
Description
Actions

Supplementary weblinks

Title
Description
Actions
Title
Description
Actions
View
Title
Description
Actions
View
Title
Description
Actions
View
Title
Description
Actions
View
Title
Description
Actions
View
Title
Description
Actions
View
Title
Description
Actions
View

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Dec 31, 2020 Version 2

Metrics

4,467
1,129
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12925238.v2
D O I: 10.26434/chemrxiv.12925238.v2 [opens in a new tab]

Funding

National Science Council of Taiwan, (ROC) for financial support in the form of Post-Doctoral Fellowship during February 2000-July 2003.

Author’s competing interest statement

There is no Competing Interests pending

Share