Organic Chemistry

O-Mesityl(sulfonyl)hydroxylamine: A Novel Reagent for Reduction of Electron Deficient α,β-Unsaturated Carbonyl Derivatives

Sudershan Reddy Gondi National Taiwan Normal University

Abstract

Hydrogenation of electron deficient ,-unsaturated carbonyl derivatives
using O-mesityl(sulfonyl)hydroxylamine in the presence of catalytic amount of ytterbium
triflate to obtain good to excellent is described.

Content

Thumbnail image of Hydrogenation manuscript 12-30-2020 ready to submit.pdf
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Supplementary material

Thumbnail image of Hydrogenation-a,b-unsaturated substrates-experimental 12-29-2020.pdf
download asset Hydrogenation-a,b-unsaturated substrates-experimental 12-29-2020.pdf 0.81 MB [opens in a new tab]
Hydrogenation-a,b-unsaturated substrates-experimental 12-29-2020
Thumbnail image of Hydrogenation-a,b-unsaturated substrates-spectral data-12-29-2020.pdf
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Hydrogenation-a,b-unsaturated substrates-spectral data-12-29-2020
Thumbnail image of Hydrogenation-Experimental on 12-28-2020, endnote ref.pdf
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Hydrogenation-Experimental on 12-28-2020, endnote ref
Thumbnail image of Hydrogenation-products NMR and Mass data on 12-28-2020.pdf
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Hydrogenation-products NMR and Mass data on 12-28-2020
Thumbnail image of Stability study of sulfonoyl hydroxylamine derivatives.pdf
download asset Stability study of sulfonoyl hydroxylamine derivatives.pdf 0.83 MB [opens in a new tab]
Stability study of sulfonoyl hydroxylamine derivatives

Supplementary weblinks