Green Synthesis: Novel method for Substituted Anilines from its Benzyl Azides

18 September 2020, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A unique and novel synthetic method was developed to generate substituted
anilines from its benzyl azides having ortho/para electron withdrawing group (EWG),
and when these groups are at meta position gives aldehyde, instead. This approach is
an inexpensive, simple, fast, efficient at room temperature. This protocol is easily
amenable to large scale preparation.

Keywords

substituted benzylazides
green chemistry
selectivity
electron withdrawing groups
substituted anilines.
extrusion of carbon.

Supplementary materials

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Azide experimental, submitted to Chemrxiv on 9-16-2020
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Azide spectra, submitted to Chemrxiv on 9-16-2020
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Supplementary weblinks

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