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Solvent Induced Enantioselectivity Reversal in a Chiral Metal Organic Framework

27 October 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Solvent induced enantioselectivity reversal is a rarely reported phenomenon in porous homochiral materials. Similar behaviour has been studied in chiral HPLC, where minor mobile phase modifications can induce elution order reversal. We report the first instance of solvent-induced enantioselectivity reversal for homochiral MOF ZnBLD, highlighting the complex enantioselectivity behaviour

Keywords

Metal organic framework
Adsorption
Enantioselective
Eantioselectivity reversal

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Version History

Oct 27, 2020 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.13138997.v1
D O I: 10.26434/chemrxiv.13138997.v1 [opens in a new tab]

Author’s competing interest statement

No conflict of interest to declare.

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