A Facially Coordinating Tris-Benzimidazole Ligand for Nonheme Iron Enzyme Models: Biomimetic or Radical Aerobic Oxidation?

David Lacy; Parami Gunasekera; Preshit Abhyankar; Samantha N. Macmillan

doi:10.26434/chemrxiv.13011617.v1

Inorganic Chemistry

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A Facially Coordinating Tris-Benzimidazole Ligand for Nonheme Iron Enzyme Models: Biomimetic or Radical Aerobic Oxidation?

28 September 2020, Version 1

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Abstract

This work describes the synthesis and characterization of new ligands and iron complexes for mononuclear nonheme iron oxygenase structural models. Catalytic studies with these new complexes and known reported catalysts highlight the need for careful control reactions when carrying out aerobic oxidations.

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