Inorganic Chemistry

Electronic Structure Modulation in Cationic Boron Formazanate Complexes

Joe Gilroy The University of Western Ontario

Abstract

The effect of charge, coordination number, and supporting ligands at boron in formazanate-based BN heterocycles is systematically explored. It is shown that the type and wavelength of the lowest-energy electronic excitation of these compounds can be modulated through structural variation at boron.

Content

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Supplementary material

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Gilroy Boron Cations SI Submitted