Stabilizing catalytic iron-oxo-clusters within nanoporous metal-organic frameworks (MOF) is a powerful strategy to prepare new active materials for the degradation of toxic chemicals, such as bisphenol A. Herein, we combine pair distribution function analysis of total X-ray scattering data and X-ray absorption spectroscopy, with computational modelling to understand the local structural nature of added redox-active iron-oxo clusters bridging neighbouring zirconia-nodes within MOF-808.
Catalytic Fe-Oxo Clusters Stabilized on the MOF-808 Metal Organicframework for the Degradation of Water Pollutants
11 September 2020, Version 1
This content is a preprint and has not undergone peer review at the time of posting.
Fe-MOF-808 ESI Platero-Prats