Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO)6]: Synthesis of Well-Defined Magnesium Benzenehexolate Complexes

Albert Paparo; K. Yuvaraj; Aidan J. R. Matthews; Iskander Douair; Laurent Maron; Cameron Jones

doi:10.26434/chemrxiv.12780428.v1

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Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO)6]: Synthesis of Well-Defined Magnesium Benzenehexolate Complexes

10 August 2020, Version 1

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Abstract

The first examples of magnesium benzenehexolate complexes are prepared by reductive hexamerizations of CO, in reactions that are initiated (or catalyzed) by [Mo(CO)₆]. These reactions are closely related to Justus von Liebig’s classical 1834 study on the reduction of CO gas with molten potassium, which yields K₆C₆O₆ (amongst other products), by an as yet unknown mechanism.

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Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO) 6 ]: Synthesis of Well‐Defined Magnesium Benzenehexolate Complexes**

Albert Paparo, K. Yuvaraj, Aidan J. R. Matthews, Iskander Douair, Laurent Maron, Cameron Jones journal article

Angewandte Chemie International Edition , Volume 60, Issue 2

Online publication date: Nov 05, 2020

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Aug 10, 2020 Version 1

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DOI

10.26434/chemrxiv.12780428.v1

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The authors declare no conflict of interest

Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO)6]: Synthesis of Well-Defined Magnesium Benzenehexolate Complexes

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