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Phase Behavior that Enables Solvent-Free Carbonate-Promoted Furoate Carboxylation

20 July 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A solvent-free transformation that enables production of polyester precursors from inedible biomass proceeds from a heterogeneous reaction mixture containing both solid and molten components. Characterization of the evolution of these component phases over the course of the reaction provides insight relevant to process design and scale-up.

Keywords

Solvent-free Chemistry
C–H Carboxylation
Phase Transitions
Sustainable Chemistry

Supplementary materials

Title
Description
Actions
Title
Furoate Phase Behavior SI
Description
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Now Published

Phase Behavior That Enables Solvent-Free Carbonate-Promoted Furoate Carboxylation [opens in a new tab]
Amy D. Frankhouser, Matthew W. Kanan journal article
The Journal of Physical Chemistry Letters , Volume 11, Issue 18
Online publication date: Aug 19, 2020

Version History

Jul 20, 2020 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12671069.v1
D O I: 10.26434/chemrxiv.12671069.v1 [opens in a new tab]

Author’s competing interest statement

The authors have no conflict of interest to declare

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