![Author ORCID: We display the ORCID iD icon alongside authors names on our website to acknowledge that the ORCiD has been authenticated when entered by the user. To view the users ORCiD record click the icon. [opens in a new tab]](https://chemrxiv.org/engage/assets/public/chemrxiv/images/logos/orcid.png)
Abstract
Terphenyl(bisamino)phosphines
have been identified as effective ligands in cationic gold(I) complexes for the
hydroamination of acetylenes. These systems are related to Buchwald phosphines
and their steric properties have been evaluated. Effective hydroamination was
noted even at low catalyst loadings and a series of cationic gold(I) complexes
has been structurally characterized clearly indicating stabilizing effects
through gold-arene interactions.
Supplementary materials
Title
ESI ChemRXiv
Description
Actions
