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Orbital Phase Perspective of Goodenough-Kanamori-Anderson Rules (GKA Rules) in Superexchange Interaction

13 November 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Goodenough-Kanamori-Anderson rules (GKA rules) in superexchange interaction discriminate the magnetic properties of two magnetic metal ions bridged with an anion. We propose here that the GKA rules can be explained in terms of the orbital phase continuity-discontinuity property of cyclic orbital interaction including direct metal-metal orbital interaction.

Keywords

superexchange interaction
orbital phase perspective
cyclic orbital interaction
orbital phase continuity and discontinuity

Supplementary materials

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GKA9y01edit2a
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Version History

Nov 13, 2019 Version 1

Version Notes

ver. 1.0 in acs format

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.10251563.v1
D O I: 10.26434/chemrxiv.10251563.v1 [opens in a new tab]

Funding

This research was funded by Gifu University.

Author’s competing interest statement

There is no conflict of interest.

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