The ring-opening oxidative amination of methylenecyclopropanes (MCPs) with diazenes catalyzed by py3TiCl2(NR) complexes is reported. This reaction selectively generates branched α-methylene imines as opposed to linear α,β-unsaturated imines, which are difficult to access via other methods
Ti-Catalyzed Ring-Opening Oxidative Amination of Methylenecyclopropanes with Diazenes
14 May 2020, Version 1
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SI MCPs Chem Sci