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Spin-Forbidden Excitation Enables Infrared Photoredox Catalysis

24 April 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We describe a new family of catalysts that undergo direct ground state singlet to excited state triplet excitation with IR light, leading to photoredox catalysis without the energy waste associated with intersystem crossing. The finding allows a mole scale reaction in batch using infrared irradiation.

Keywords

Photoredox Catalysis
Infrared
Scale-up

Supplementary materials

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Version History

Apr 24, 2020 Version 1

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License

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12124215.v1
D O I: 10.26434/chemrxiv.12124215.v1 [opens in a new tab]

Funding

GM125206

Author’s competing interest statement

No conflict

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