Unraveling Minimum Active Units and Substrate Activation for Carbon Nitride in Photocatalytic Oxidation Reactions

23 April 2020, Version 1
This content is a preprint and has not undergone peer review at the time of posting.


Covalent bonded carbon nitride (CN) has stimulated extensive attentions from photosynthesis to optoelectronics. However, the acquisition of correct numbers beyond stoichiometry and composition remains indefinable. Moreover, the electronic coupling by the substrates to the photoexcitation processes in value-added oxidation reactions is essential, but still poorly understood. Herein, we report by far the minimum active structure of CN by constructing fragments consisting of melem (M1) and its incomplete condensed form with cyanide termination (M2). Surprisingly, such configuration endowed a boosted activity of 11 times of traditional bulk CN in photocatalytic oxidation of tetracycline as a showcase application of water cleaning and sanitation. The mechanism studies disclosed that M1 and M2 were primarily responsible for light absorption and charge separation, respectively; meanwhile the electronic coupling by the O2 substrate participated the photoexcited processes thus synergistically enhanced the photocatalytic reactions.


carbon nitride
microwave Assisted Synthesis
substrate activation
electron coupling
light absorption
charge seperation
water purification

Supplementary materials



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